Semiclassical approximation with zero velocity trajectories
نویسندگان
چکیده
منابع مشابه
Semiclassical Propagation of Wavepackets with Complex Trajectories
We derive a semiclassical approximation for the time evolution of an originally gaussian wave packet in terms of complex trajectories. We also consider additional approximations replacing the complex trajectories by real ones. These yield three different semiclassical formulae involving different real trajectories. One of these formulae is Heller’s thawed gaussian approximation. The other appro...
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ژورنال
عنوان ژورنال: Chemical Physics
سال: 2007
ISSN: 0301-0104
DOI: 10.1016/j.chemphys.2007.05.014